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Material Specification

Alloy 25

Alloy 25 Fasteners
22Cr-25NiWCoCu Austenitic Heat Resistant Steel – Advanced Boiler Service to 750°C

S Alloy 25 (Sanicro 25) Fasteners

Buy S Alloy 25 (Sanicro 25 / UNS S31035 / EN 1.4990) tube, pipe, bar, fittings and custom machined components from Exotic Alloy. Alloy 25 is a 22.5% chromium, 25% nickel austenitic heat-resistant steel with deliberate tungsten, cobalt, copper, niobium and nitrogen additions, developed for the superheaters and reheaters of advanced high-efficiency pulverised-coal steam boilers where creep strength and steam-side oxidation resistance both govern.

Exotic Alloy supplies Alloy 25 to ASTM A213 and ASTM A312 with ASME Boiler and Pressure Vessel Code Case 2753-1 and 2752-1 acceptance, VdTÜV material data sheet 555 and Chinese pressure vessel approval CSCBPV BV-ME-210, in the solution-annealed condition with full EN 10204 3.1 material test certificates. Maximum use temperature is 750°C, with the alloy developed for sustained service around 700°C.

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Product Range

Alloy 25 Fasteners Available

Alloy 25 Hex Bolts
Alloy 25
Hex Bolts
Alloy 25 Heavy Hex Bolts
Alloy 25
Heavy Hex Bolts
Alloy 25 Stud Bolts
Alloy 25
Stud Bolts
Alloy 25 Threaded Rods
Alloy 25
Threaded Rods
Alloy 25 Anchor Bolts
Alloy 25
Anchor Bolts
Alloy 25 Hex Nuts
Alloy 25
Hex Nuts
Alloy 25 Washers
Alloy 25
Washers
Alloy 25 Cotter Pins
Alloy 25
Cotter Pins
Alloy 25 Springs
Alloy 25
Springs
Alloy 25 Circlips
Alloy 25
Circlips
Alloy 25 Coated Fasteners
Alloy 25
Coated Fasteners
Alloy 25 Custom Spacers
Alloy 25
Custom Spacers
Technical Data

Alloy 25 Specifications

Chemical Composition — S Alloy 25 (Sanicro 25) (wt. %)
ElementFeCrNiWCuCoNbNC
Nominal %Balance22.525.03.63.01.50.50.23≤ 0.1
Mechanical Properties — S Alloy 25 (Sanicro 25)
ConditionUTS (MPa)YS 0.2% (MPa)Elongation (%)Hardness
Solution Annealed at 20°C — Rp0.2 Minimum≥ 680≥ 310≥ 40Approx. 185 HV
Solution Annealed at 20°C — Rp1.0 Minimum≥ 680≥ 355≥ 40Approx. 185 HV
Maximum Use Temperature–––750°C (1382°F)
Design Service Temperature–––Around 700°C
Physical Properties
Density8.32 g/cm³ (0.29 lb/in³)
Modulus of Elasticity197 GPa at 20°C
Specific Heat Capacity470 J/kg·°C at 20°C
Thermal Conductivity12 W/m·°C at 20°C
Thermal Expansion14.5 × 10−⁶/°C (30–100°C)
Electrical Resistivity0.98 µΩ·m at 20°C
Equivalent Grades & Standards
UNSEN NumberEN NameCommon Name
S31035 1.4990 X7NiCrWCuCoNb25-23-3-3-2 Sanicro 25

Key Specifications: ASTM A213 and ASTM A312 (Seamless Tube & Pipe) / ASME Boiler and Pressure Vessel Code Case 2753-1 (Section I) and 2752-1 (Section VIII Division 1) / VdTÜV material data sheet 555 / European Particular Material Appraisal / China Pressure Vessel Approval CSCBPV BV-ME-210.

Machinability: Alloy 25 is a fully austenitic steel and machines accordingly — it work-hardens readily and its thermal conductivity of only 12 W/m·°C concentrates heat at the cutting edge. Use rigid setups, sharp positive-rake carbide tooling at moderate speeds, heavy positive feeds and a generous depth of cut so the tool engages beneath the previously worked layer, with continuous flood coolant. Light finishing passes riding on work-hardened metal should be avoided.

Welding: weldability is good, with TIG/GTAW the first-choice process and MMA/SMAW and gas-shielded arc welding also suitable. Heat input should be kept below 1.0 kJ/mm and interpass temperature below 100°C, using a string bead technique. Because the alloy has low thermal conductivity and high thermal expansion, welding sequence should be planned in advance to limit distortion; solution annealing after welding relieves residual stress where that matters. Recommended fillers are ISO 18274 S Ni 6617 / AWS A5.14 ERNiCrCoMo-1 for TIG and MIG, and ISO 14172 E Ni 6117 / AWS A5.11 ENiCrCoMo-1 for MMA.

Forming: the alloy has good fabricability for a creep-strength austenitic and is supplied cold pilgered, solution annealed and white pickled in the common superheater and reheater sizes.

Heat Treatment: solution anneal at 1180–1250°C followed by quenching. Note that this is a markedly higher solution temperature than conventional austenitic stainless steels require, which is necessary to dissolve the niobium and tungsten-bearing precipitates and restore full creep strength; annealing at stainless-steel temperatures will not produce compliant material.

Alloy 25 was developed for the steam and flue-gas side of an advanced coal-fired boiler, and its published performance reflects that. Air oxidation testing at 650°C and 750°C for up to 3000 hours shows very low mass change, and oxidation resistance in aqueous steam is very good at 600°C over 500 hours and at 700°C over 1000 hours. Hot corrosion resistance in coal-ash environments is very good, which is the mechanism that limits life in pulverised-coal superheaters. The 22.5% chromium supports both steam oxidation and hot corrosion resistance, while roughly 25% nickel together with the high nitrogen content keeps the face-centred-cubic austenitic structure stable in long-term service. Creep strength is very high, and the austenitic structure gives very good impact strength including at cryogenic temperatures.

The S alloy numbers are brand designations, not UNS numbers, and they do not map onto the alloy numbers used elsewhere in this catalogue. Alloy 41 in this family is UNS N08825 — the alloy sold generically as 825 — not the Rene 41 superalloy. Alloy 60 is UNS N06625, which is alloy 625, while Alloy 70 is UNS N06600, which is alloy 600. Alloy 31HT is UNS N08810/N08811, the 800H and 800HT chemistry. Always confirm the UNS number rather than ordering against the brand number alone; the S Alloys cross-reference table sets out the full mapping.

Sanicro is a trademark of Alleima, the former Sandvik Materials Technology business. Exotic Alloy is an independent manufacturer and is not affiliated with or endorsed by Alleima or Sandvik; the designation is used here solely to identify the alloy chemistry, which is defined by the UNS and EN numbers given above.

Key Characteristics

  • Very high creep strength for advanced high-efficiency boiler service.
  • Tungsten, cobalt, copper, niobium and nitrogen all contribute strengthening.
  • Very good hot corrosion resistance in coal-ash environments.
  • Very low mass change in air oxidation testing at 650°C and 750°C.
  • Structurally stable austenite with good impact strength to cryogenic temperatures.

Typical Applications

  • Power generation: superheater and reheater tubing in advanced coal boilers.
  • Boiler construction: high-temperature header and pipework components.
  • Fastener assemblies and supports for superheater and reheater hardware.
  • Waste-to-energy and biomass plant exposed to ash-side corrosion.
  • High-temperature process piping requiring long-term creep strength.